Electro-vibrational Ising-type model for spin crossover in binuclear molecules
| dc.contributor.author | A Metatla | |
| dc.contributor.author | H Latelli | |
| dc.date.accessioned | 2021-02-10T09:56:55Z | |
| dc.date.available | 2021-02-10T09:56:55Z | |
| dc.date.issued | 2019 | |
| dc.description.abstract | spin crossover in binuclear molecule is investigated using an Ising-type model, including the intramolecular vibrations. The spin transition curve of [Fe(bt)(NCS)2]2bpym complex which presents a two-step transition plateau is well described by the above model. We show that the equilibrium low-spin/high-spin temperature Teq is independent of the vibration frequencies of the intermediate state (HS–LS or LS–HS) xLHS. In addition, a large values of LS–LS state vibration frequencies xLLS lead to an evident two-step transition plateau. | en_US |
| dc.identifier.uri | http://dspace.univ-msila.dz:8080//xmlui/handle/123456789/23781 | |
| dc.publisher | Université de M'sila | en_US |
| dc.subject | Spin crossover; Ising-type model; Binuclear molecules; Two-step spin transition | en_US |
| dc.title | Electro-vibrational Ising-type model for spin crossover in binuclear molecules | en_US |
| dc.type | Article | en_US |